Isotopes of lutetium
| ||||||||||||||||||||||||||||||||||||
Standard atomic weight Ar°(Lu) | ||||||||||||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Naturally occurring lutetium (71Lu) is composed of one stable isotope 175Lu (97.40% natural abundance) and one long-lived radioisotope, 176Lu with a half-life of 37 billion years (2.60% natural abundance). Forty synthetic radioisotopes have been added from 149Lu to 190Lu, with the most stable being 174Lu with a half-life of 3.31 years and 173Lu with a half-life of 1.37 years. All of the remaining radioactive isotopes have half-lives that are less than 9 days, and the majority of these have half-lives that are less than half an hour. Of the meta states known for this element, the most stable are 177m3Lu (t1/2 160.4 days) and 174mLu (t1/2 142 days).
The primary decay mode before the most abundant stable isotope, 175Lu, is electron capture (with some alpha and positron emission), leading to ytterbium or less often thulium isotopes, and the primary mode after is beta emission giving hafnium isotopes.
All isotopes of lutetium are either radioactive or, for the lone stable isotopes 175Lu, observationally stable, meaning that it is predicted to be radioactive (to alpha decay) but no decay has been observed.[4]
List of isotopes
Nuclide [n 1] |
Z | N | Isotopic mass (Da)[5] [n 2][n 3] |
Half-life[1] [n 4][n 5] |
Decay mode[1] [n 6] |
Daughter isotope [n 7] |
Spin and parity[1] [n 8][n 5] |
Natural abundance (mole fraction) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy[n 5] | Normal proportion[1] | Range of variation | |||||||||||||||||
149Lu[6] | 71 | 78 | 450+170 −100 ns |
p | 148Yb | 11/2− | |||||||||||||
150Lu | 71 | 79 | 149.97341(32)# | 45(3) ms | p | 149Yb | (5−) | ||||||||||||
150mLu | 22(5) keV | 40(7) μs | p | 149Yb | (8+) | ||||||||||||||
151Lu | 71 | 80 | 150.96747(32)# | 78.4(9) ms | p (?%) | 150Yb | 11/2− | ||||||||||||
β+ (?%) | 151Yb | ||||||||||||||||||
151mLu | 57(4) keV | 16.0(5) μs | p | 150Yb | 3/2+ | ||||||||||||||
152Lu | 71 | 81 | 151.96412(21)# | 650(70) ms | β+ (85%) | 152Yb | (4−, 5−, 6−) | ||||||||||||
β+, p (15%) | 151Tm | ||||||||||||||||||
153Lu | 71 | 82 | 152.95880(16) | 0.9(2) s | α (?%) | 149Tm | 11/2− | ||||||||||||
β+ (?%) | 153Yb | ||||||||||||||||||
153m1Lu | 80(5) keV | 1# s | IT | 153Lu | 1/2+ | ||||||||||||||
153m2Lu | 2502.5(4) keV | >0.1 μs | IT | 153Lu | 23/2− | ||||||||||||||
153m3Lu | 2632.9(5) keV | 15(3) μs | IT | 153Lu | 27/2− | ||||||||||||||
154Lu | 71 | 83 | 153.95742(22)# | 1# s | (2−) | ||||||||||||||
154m1Lu | 62(12) keV | 1.12(8) s | β+ (?%) | 154Yb | (9+) | ||||||||||||||
β+p (?%) | 153Tm | ||||||||||||||||||
β+α (?%) | 150Er | ||||||||||||||||||
154m2Lu | 2724(100)# keV | 35(3) μs | IT | 154Lu | (17+) | ||||||||||||||
155Lu | 71 | 84 | 154.954326(21) | 68(2) ms | α (90%) | 151Tm | 11/2− | ||||||||||||
β+ (10%) | 155Yb | ||||||||||||||||||
155m1Lu | 21(4) keV | 138(9) ms | α (76%) | 151Tm | 1/2+ | ||||||||||||||
β+ (24%) | 155Yb | ||||||||||||||||||
155m2Lu | 1780.3(18) keV | 2.69(3) ms | α | 151Tm | 25/2−# | ||||||||||||||
156Lu | 71 | 85 | 155.953087(58) | 494(12) ms | α | 152Tm | (2)− | ||||||||||||
156m1Lu[n 9] | 10(250) keV | 198(2) ms | α | 152Tm | 10+ | ||||||||||||||
156m2Lu | 2611(250) keV | 179(4) ns | IT | 156Lu | 19− | ||||||||||||||
157Lu | 71 | 86 | 156.950145(13) | 7.7(20) s | β+ (?%) | 157Yb | (1/2+) | ||||||||||||
α (?%) | 153Tm | ||||||||||||||||||
157mLu | 20.9(20) keV | 4.79(12) s | β+ (92.3%) | 157Yb | (11/2−) | ||||||||||||||
α (7.7%) | 153Tm | ||||||||||||||||||
158Lu | 71 | 87 | 157.949316(16) | 10.6(3) s | β+ (99.09%) | 158Yb | (2)− | ||||||||||||
α (0.91%) | 154Tm | ||||||||||||||||||
159Lu | 71 | 88 | 158.946636(40) | 12.1(10) s | β+ | 159Yb | 1/2+ | ||||||||||||
α (rare) | 155Tm | ||||||||||||||||||
160Lu | 71 | 89 | 159.946033(61) | 36.1(3) s | β+ | 160Yb | 2−# | ||||||||||||
160mLu[n 9] | 0(100)# keV | 40(1) s | β+ | 160Yb | |||||||||||||||
161Lu | 71 | 90 | 160.943572(30) | 77(2) s | β+ | 161Yb | 1/2+ | ||||||||||||
161mLu | 182(5)# keV | 7.3(4) ms | IT | 161Lu | (9/2−) | ||||||||||||||
162Lu | 71 | 91 | 161.943283(81) | 1.37(2) min | β+ | 162Yb | 1− | ||||||||||||
162m1Lu[n 9] | 120(200)# keV | 1.5 min | β+ | 162Yb | 4−# | ||||||||||||||
162m2Lu[n 10] | 300(200)# keV | 1.9 min | 9−# | ||||||||||||||||
163Lu | 71 | 92 | 162.941179(30) | 3.97(13) min | β+ | 163Yb | 1/2+ | ||||||||||||
164Lu | 71 | 93 | 163.941339(30) | 3.14(3) min | β+ | 164Yb | 1− | ||||||||||||
165Lu | 71 | 94 | 164.939407(28) | 10.74(10) min | β+ | 165Yb | 1/2+ | ||||||||||||
166Lu | 71 | 95 | 165.939859(32) | 2.65(10) min | β+ | 166Yb | 6− | ||||||||||||
166m1Lu | 34.37(22) keV | 1.41(10) min | β+ (58%) | 166Yb | 3− | ||||||||||||||
IT (42%) | 166Lu | ||||||||||||||||||
166m2Lu | 43.0(4) keV | 2.12(10) min | β+ (90%) | 166Yb | 0− | ||||||||||||||
IT (10%) | 166Lu | ||||||||||||||||||
167Lu | 71 | 96 | 166.938243(40) | 51.5(10) min | β+ | 167Yb | 7/2+ | ||||||||||||
167mLu | 50(40)# keV | >1 min | 1/2+ | ||||||||||||||||
168Lu | 71 | 97 | 167.938730(41) | 5.5(1) min | β+ | 168Yb | 6− | ||||||||||||
168mLu | 160(40) keV | 6.7(4) min | β+ | 168Yb | 3+ | ||||||||||||||
169Lu | 71 | 98 | 168.9376458(32) | 34.06(5) h | β+ | 169Yb | 7/2+ | ||||||||||||
169mLu | 29.0(5) keV | 160(10) s | IT | 169Lu | 1/2− | ||||||||||||||
170Lu | 71 | 99 | 169.938479(18) | 2.012(30) d | β+ | 170Yb | 0+ | ||||||||||||
170mLu | 92.91(9) keV | 670(100) ms | IT | 170Lu | 4− | ||||||||||||||
171Lu | 71 | 100 | 170.9379186(20) | 8.247(23) d | β+ | 171Yb | 7/2+ | ||||||||||||
171mLu | 71.13(8) keV | 79(2) s | IT | 171Lu | 1/2− | ||||||||||||||
172Lu | 71 | 101 | 171.9390913(25) | 6.70(3) d | β+ | 172Yb | 4− | ||||||||||||
172m1Lu | 41.86(4) keV | 3.7(5) min | IT | 172Lu | 1− | ||||||||||||||
172m2Lu | 65.79(4) keV | 332(20) ns | IT | 172Lu | (1)+ | ||||||||||||||
172m3Lu | 109.41(10) keV | 440(12) μs | IT | 172Lu | (1)+ | ||||||||||||||
172m4Lu | 213.57(17) keV | 150 ns | IT | 172Lu | (6−) | ||||||||||||||
173Lu | 71 | 102 | 172.9389357(17) | 1.37(1) y | EC | 173Yb | 7/2+ | ||||||||||||
173mLu | 123.672(13) keV | 74.2(10) μs | IT | 173Lu | 5/2− | ||||||||||||||
174Lu | 71 | 103 | 173.9403428(17) | 3.31(5) y | β+ | 174Yb | 1− | ||||||||||||
174m1Lu | 170.83(5) keV | 142(2) d | IT (99.38%) | 174Lu | 6− | ||||||||||||||
EC (0.62%) | 174Yb | ||||||||||||||||||
174m2Lu | 240.818(4) keV | 395(15) ns | IT | 174Lu | 3+ | ||||||||||||||
174m3Lu | 365.183(6) keV | 145(3) ns | IT | 174Lu | 4− | ||||||||||||||
174m4Lu | 1855.7(5) keV | 194(24) ns | IT | 174Lu | 13+ | ||||||||||||||
174m5Lu | 4068.4(9) keV | 97(10) ns | IT | 174Lu | (21+) | ||||||||||||||
174m6Lu | 5849.6(9) keV | 242(19) ns | IT | 174Lu | (26−) | ||||||||||||||
175Lu | 71 | 104 | 174.9407772(13) | Observationally stable[n 11] | 7/2+ | 0.97401(13) | |||||||||||||
175m1Lu | 353.48(13) keV | 1.49(7) μs | IT | 175Lu | 5/2− | ||||||||||||||
175m2Lu | 1392.4(4) keV | 984(30) μs | IT | 175Lu | 19/2+ | ||||||||||||||
176Lu[n 12][n 13] | 71 | 105 | 175.9426917(13) | 3.701(17)×1010 y | β−[n 14] | 176Hf | 7− | 0.02599(13) | |||||||||||
176m1Lu | 122.845(4) keV | 3.664(19) h | β− (99.90%) | 176Hf | 1− | ||||||||||||||
EC (0.095%) | 176Yb | ||||||||||||||||||
176m2Lu | 1514.5(5) keV | 312(69) ns | IT | 176Lu | 12+ | ||||||||||||||
176m3Lu | 1587.8(6) keV | 40(3) μs | IT | 176Lu | 14+ | ||||||||||||||
177Lu | 71 | 106 | 176.9437636(13) | 6.6443(9) d | β− | 177Hf | 7/2+ | ||||||||||||
177m1Lu | 150.3984(10) keV | 130.1(24) ns | IT | 177Lu | 9/2− | ||||||||||||||
177m2Lu | 569.6721(15) keV | 155(7) μs | IT | 177Lu | 1/2+ | ||||||||||||||
177m3Lu | 970.1757(24) keV | 160.4(3) d | β− (77.30%) | 177Hf | 23/2− | ||||||||||||||
IT (22.70%) | 177Lu | ||||||||||||||||||
177m4Lu | 2771.7(5) keV | 625(62) ns | IT | 177Lu | 33/2+ | ||||||||||||||
177m5Lu | 3530.4(6) keV | 6(2) μs | IT | 177Lu | 39/2− | ||||||||||||||
178Lu | 71 | 107 | 177.9459601(24) | 28.4(2) min | β− | 178Hf | 1+ | ||||||||||||
178mLu | 123.8(26) keV | 23.1(3) min | β− | 178Hf | 9− | ||||||||||||||
179Lu | 71 | 108 | 178.9473330(55) | 4.59(6) h | β− | 179Hf | 7/2+ | ||||||||||||
179mLu | 592.4(4) keV | 3.1(9) ms | IT | 179Lu | 1/2+ | ||||||||||||||
180Lu | 71 | 109 | 179.949891(76) | 5.7(1) min | β− | 180Hf | 5+ | ||||||||||||
180m1Lu | 13.9(3) keV | ~1 s | 3− | ||||||||||||||||
180m2Lu | 624.0(5) keV | >1 ms | IT | 180Lu | (9−) | ||||||||||||||
181Lu | 71 | 110 | 180.95191(14) | 3.5(3) min | β− | 181Hf | 7/2+# | ||||||||||||
182Lu | 71 | 111 | 181.95516(22)# | 2.0(2) min | β− | 182Hf | 1−# | ||||||||||||
183Lu | 71 | 112 | 182.957363(86) | 58(4) s | β− | 183Hf | 7/2+# | ||||||||||||
184Lu | 71 | 113 | 183.96103(22)# | 20(3) s | β− | 184Hf | (3+) | ||||||||||||
185Lu | 71 | 114 | 184.96354(32)# | 20# s [>300 ns] |
7/2+# | ||||||||||||||
186Lu | 71 | 115 | 185.96745(43)# | 6# s [>300 ns] |
|||||||||||||||
187Lu | 71 | 116 | 186.97019(43)# | 7# s [>300 ns] |
7/2+# | ||||||||||||||
188Lu | 71 | 117 | 187.97443(43)# | 1# s [>300 ns] |
|||||||||||||||
189Lu[8] | 71 | 118 | |||||||||||||||||
190Lu[9] | 71 | 119 | |||||||||||||||||
This table header & footer: |
- ^ mLu – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ Bold half-life – nearly stable, half-life longer than age of universe.
- ^ a b c # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^
Modes of decay:
EC: Electron capture
IT: Isomeric transition
p: Proton emission - ^ Bold symbol as daughter – Daughter product is stable.
- ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ a b c Order of ground state and isomer is uncertain.
- ^ Discovery of this isotope is disputed.
- ^ Believed to undergo α decay to 171Tm
- ^ primordial radionuclide
- ^ Used in lutetium-hafnium dating
- ^ Theoretically capable of electron capture to 176Yb[7] or α decay to 172Tm
Lutetium-177
Lutetium (177Lu) chloride, sold under the brand name Lumark among others, is used for radiolabeling other medicines, either as an anti-cancer therapy or for scintigraphy (medical radio-imaging). Its most common side effects are anaemia (low red blood cell counts), thrombocytopenia (low blood platelet counts), leucopenia (low white blood cell counts), lymphopenia (low levels of lymphocytes, a particular type of white blood cell), nausea (feeling sick), vomiting and mild and temporary hair loss.[10][11]
See also
Daughter products other than lutetium
References
- ^ a b c d e Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3) 030001. doi:10.1088/1674-1137/abddae.
- ^ "Standard Atomic Weights: Lutetium". CIAAW. 2024.
- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ Belli, P.; Bernabei, R.; Danevich, F. A.; et al. (2019). "Experimental searches for rare alpha and beta decays". European Physical Journal A. 55 (8): 140–1–140–7. arXiv:1908.11458. Bibcode:2019EPJA...55..140B. doi:10.1140/epja/i2019-12823-2. ISSN 1434-601X. S2CID 201664098.
- ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3) 030003. doi:10.1088/1674-1137/abddaf.
- ^ Auranen, K. (16 March 2022). "Nanosecond-Scale Proton Emission from Strongly Oblate-Deformed 149Lu". Physical Review Letters. 128 (11): 2501. Bibcode:2022PhRvL.128k2501A. doi:10.1103/PhysRevLett.128.112501. PMID 35363028. S2CID 247855967.
- ^ Nozzoli, Francesco; Ghezzer, Luigi Ernesto; Nicolaidis, Riccardo; Iuppa, Roberto; Zuccon, Paolo; et al. (European Nuclear Physics Conference (EuNPC 2022)) (8 December 2023). "Investigation of Electron Capture in 176Lu with a LYSO crystal scintillator". EPJ Web of Conf. 290 (01002). arXiv:2211.15203. doi:10.1051/epjconf/202329001002.
- ^ Haak, K.; Tarasov, O. B.; Chowdhury, P.; et al. (2023). "Production and discovery of neutron-rich isotopes by fragmentation of 198Pt". Physical Review C. 108 (34608): 034608. Bibcode:2023PhRvC.108c4608H. doi:10.1103/PhysRevC.108.034608. S2CID 261649436.
{{cite journal}}
: CS1 maint: article number as page number (link) - ^ Tarasov, O. B.; Gade, A.; Fukushima, K.; et al. (2024). "Observation of New Isotopes in the Fragmentation of 198Pt at FRIB". Physical Review Letters. 132 (072501). doi:10.1103/PhysRevLett.132.072501.
- ^ "Lumark EPAR". European Medicines Agency. 17 September 2018. Retrieved 7 May 2020. Text was copied from this source for which copyright belongs to the European Medicines Agency. Reproduction is authorized provided the source is acknowledged.
- ^ "EndolucinBeta EPAR". European Medicines Agency (EMA). 17 September 2018. Retrieved 7 May 2020. Text was copied from this source for which copyright belongs to the European Medicines Agency. Reproduction is authorized provided the source is acknowledged.