Hydrodynamic voltammetry

In analytical chemistry, hydrodynamic voltammetry is a form of voltammetry in which the analyte solution flows relative to a working electrode.[1][2] In many voltammetry techniques, the solution is intentionally left still to allow diffusion-controlled mass transfer. When a solution is made to flow, through stirring or some other physical mechanism, it is very important to the technique to achieve a very controlled flux or mass transfer in order to obtain predictable results. These methods are types of electrochemical studies which use potentiostats to investigate reaction mechanisms related to redox chemistry among other chemical phenomenon.[3][4][5][6]

Structure

Most experiments involve a three electrode setup but the setup configuration varies widely. All cell configurations create a laminar flow of solution across the working electrode(s) producing a steady-state current determined by solution flow rather than diffusion. The resulting current can be mathematically predicted and modeled. Among the most common hydrodynamic setup involves the working electrodes rotating to create a laminar flow of solution across the electrode surface. Both rotating disk electrodes (RDE) and rotating ring-disk electrodes (RRDE) are examples where the working electrode rotates. Other configurations, such as flow cells, use pumps to direct solution at or across the working electrode(s).

Distinction

Hydrodynamic techniques are distinct from still and unstirred experiments such as cyclic voltammetry where the steady-state current is limited by the diffusion of substrate. Experiments are not however limited to linear sweep voltammetry. The configuration of many cells takes the substrate from one working electrode across another, RRDE for example. The potential of one electrode can be varied as the other is held constant or varied. The flow rate can also be varied to adjust the temporal gap the substrates experiences between working electrodes.

See also

References
  1. Douglas A. Skoog; F. James Holler; Stanley R. Crouch (27 January 2017). Principles of Instrumental Analysis. Cengage Learning. pp. 660–. ISBN 978-1-305-57721-3.
  2. Richard G. Compton; Craig E. Banks (2011). Understanding Voltammetry. World Scientific. pp. 427–. ISBN 978-1-84816-586-1.
  3. Bard, A.J.; Faulkner, L.R. Electrochemical Methods: Fundamentals and Applications. New York: John Wiley & Sons, 2nd Edition, 2000 ISBN 0-471-40521-3.
  4. Cynthia G. Zoski (Editor) Handbook of Electrochemistry. Elsevier, 2007 ISBN 0-444-51958-0
  5. Peter T. Kissinger, William R. Heineman Laboratory Techniques in Electroanalytical Chemistry. CRC Press, 1996 ISBN 0-8247-9445-1
  6. Douglas A. Skoog, F. James Holler, Timothy A. Nieman Principles of Instrumental Analysis. Harcourt Brace College Publishers, 1998 ISBN 0-03-002078-6.
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