Subhalide

In chemistry, subhalide usually refers to inorganic compounds that have a low ratio of halide to metal, made possible by metal–metal bonding (or element–element bonding for nonmetals), sometimes extensive. Many compounds meet this definition.

Examples

The normal halide of boron is BF3. Boron forms many subhalides: several B2X4, including B2F4; also BF. Aluminium forms a variety of subhalides. For gallium, adducts of Ga2Cl4 are known. Phosphorus subhalides include P2I4, P4Cl2, and P7Cl3 (structurally related to [P7]3−). For bismuth, the compound originally described as bismuth monochloride was later shown to consist of [Bi9]5+ clusters and chloride anions.[1] There are many tellurium subhalides, including Te3Cl2, Te2X (X = Cl, Br, I), and two forms of TeI.[2]

References
  1. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  2. Zhengtao Xu "Recent Developments in Binary Halogen–Chalcogen Compounds, Polyanions and Polycations" in Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium, Francesco Devillanova, Editor, 2006, RSC. pp. 381-416. Royal Society doi:10.1039/9781847557575-00455
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