Supermicelle

Supermicelle is a hierarchical micelle structure (supramolecular assembly) where individual components are also micelles. Supermicelles are formed via bottom-up chemical approaches, such as self-assembly of long cylindrical micelles into radial cross-, star- or dandelion-like patterns in a specially selected solvent; solid nanoparticles may be added to the solution to act as nucleation centers and form the central core of the supermicelle. The stems of the primary cylindrical micelles are composed of various block copolymers connected by strong covalent bonds; within the supermicelle structure they are loosely held together by hydrogen bonds, electrostatic or solvophobic interactions.[1][2]

References
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  1. Li, Xiaoyu; Gao, Yang; Boott, Charlotte E.; Winnik, Mitchell A.; Manners, Ian (2015). "Non-covalent synthesis of supermicelles with complex architectures using spatially confined hydrogen-bonding interactions". Nature Communications. 6: 8127. Bibcode:2015NatCo...6E8127L. doi:10.1038/ncomms9127. PMC 4569713. PMID 26337527.
  2. Gould, Oliver E.C.; Qiu, Huibin; Lunn, David J.; Rowden, John; Harniman, Robert L.; Hudson, Zachary M.; Winnik, Mitchell A.; Miles, Mervyn J.; Manners, Ian (2015). "Transformation and patterning of supermicelles using dynamic holographic assembly". Nature Communications. 6: 10009. Bibcode:2015NatCo...610009G. doi:10.1038/ncomms10009. PMC 4686664. PMID 26627644.
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